Tech Briefs

Savannah River National Laboratory

FILMS: Fullerenes Improved with Light Modification for Superconductivity

Savannah River National Laboratory (SRNL) is currently in the proof of concept stage with observed preliminary results on improved performance based on higher purity. SRNL has begun to design experiments to bench-scale tested this method on a prototype.

Potential applications with NASA and DARPA. Other possible applications would be levitation for rail transportation, superconducting coils for magnetization, electric power generators, and magnetic storage.

Background

The addition of photo-excitation to an existing metal intercalated and/or hydrogenated fullerene has the ability to significantly increase the number of available charge carriers and/or phonons in the conduction band. The change in carrier density and phonon coupling capability may have a multivariate effect including the increase in the critical temperature at a constant field, creating a superconducting hysteresis over a changing magnetic field, decrease in stabilizing magnetic field required for the onset of superconductivity, and increase in the stability of superconductivity for over a larger magnetic field.

The degree of improvement and the optical energy required is dependent on the phase purity of material, degree of lattice mobility with light, and the ability to overcome the thermoelectric barrier in achieving zero resistivity all leading to various changes in onset of superconductivity. We estimate the improvement for the onset of superconductivity to be approximately 10-25 Kelvin higher than without illumination. In the best materials such as Rb3C60 and NaRbCsC60, this increase could produce materials with onset of superconductivity as high as 77 Kelvin (liquid nitrogen).

Additionally, with operation at liquid nitrogen temperatures could also compete with metal oxide superconductors utilized in various applications.

At a glance

  • Organic-based superconductors
  • Cost-effective materials
  • Light-enhanced superconductivity
  • Applicable for supercomputers
  • U. S. Patent 9,685,600 B2

Stage of development

SRNL is currently in the proof of concept stage with observed preliminary results on improved performance based on higher purity. SRNL has begun to design experiments to bench-scale tested this method on a prototype.

Potential applications with NASA and DARPA. Other possible applications would be levitation for rail transportation, superconducting coils for magnetization, electric power generators, and magnetic storage.

A patent has been filed with the U. S. Patent and Trademark Office.

Partnering opportunities

SRNL invites interested companies with proven capabilities in this area of expertise to develop commercial applications for this process or product under a cooperative research and development agreement or licensing agreement. Companies interested in licensing will be requested to submit a business plan setting forth company qualifications, strategies, activities, and milestones for commercializing this invention. Qualifications should include past experience at bringing similar products to market, reasonable schedule for product launch, sufficient manufacturing capacity, established distribution networks, and evidence of sufficient financial resources for product development and launch.

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Contact Information

Savannah River National Laboratory
E-mail: partnerships@srnl.doe.gov